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41.
Wen-Wen Zi Zihao Gao Prof. Jun Zhang Bao-Xun Zhao Xian-Shu Cai Prof. Hong-Bin Du Prof. Fei-Jian Chen 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(10):3976-3979
Extra-large-pore zeolites for processing large molecules have long been sought after by both the academia and industry. However, the synthesis of these materials, particularly extra-large-pore pure silica zeolites, remains a big challenge. Herein we report the synthesis of a new extra-large-pore silica zeolite, designated NUD-6, by using an easily synthesized aromatic organic cation as structure-directing agent. NUD-6 possesses an intersecting 16×8×8-membered ring pore channel system constructed by four-connected (Q4) and unusual three-connected (Q3) silicon species. The organic cations in NUD-6 can be removed in nitric acid to yield a porous material with high surface area and pore volume. The synthesis of NUD-6 presents a feasible means to prepare extra-large pore silica zeolites by using assembled aromatic organic cations as structure-directing agents. 相似文献
42.
通过静电吸引策略将具有高度分散性的原子精确纳米团簇[Pd3Cl(PPh2)2(PPh3)3]+(Pd3Cl)负载在介孔SBA-15棒上。结构明确的Pd3Cl/SBA-15催化剂在以水作为溶剂以及温和的反应条件下对催化Sonogashira碳-碳偶联反应展现了较好的催化性能以及循环性。在此基础上,我们研究了Pd3Cl团簇结构与性能之间的关系,并证实内核的Pdδ+(0<δ<2)与配体之间的协同效应是催化反应的关键。 相似文献
43.
Journal of Solid State Electrochemistry - A novel electrochromic polymer poly(2,3-dimethyl-2,3-dihydrothieno[3,4-b][1,4]dioxine) (PEDOT-Me2) based on 3,4-ethylenedioxythiophene (EDOT) with... 相似文献
44.
Zhang Jiaqing Zhang Bosi Li Wenjie Ouyang Benhong Fan Minghao Wang Haoming 《Journal of Thermal Analysis and Calorimetry》2020,140(6):2749-2756
Journal of Thermal Analysis and Calorimetry - The burning process and typical fire parameters of power-cable silicon ointment were explored experimentally using a cone calorimeter, and the effects... 相似文献
45.
Electronic Stability of Bimetallic Au2@Cu6 Nanocluster: Closed-Shell Interaction and Multicenter Bonding 下载免费PDF全文
Metallophilic interaction is a unique type of weak intermolecular interaction, where the electronic configuration of two metal atoms is closed shell. Despite its significance in multidisciplinary fields, the nature of metallophilic interaction is still not well understood. In this work, we investigated the electronic structures and bonding characteristic of bimetallic Au\begin{document}$ _{2} $\end{document} @Cu\begin{document}$ _{6} $\end{document} nanocluster through density functional theory method, which was reported in experiments recently [Angew. Chem. Int. Ed. 55 , 3611 (2016)]. In general thinking, interaction between two moieties of (CuSH)\begin{document}$ _{6} $\end{document} ring and (Au\begin{document}$ _{2} $\end{document} PH\begin{document}$ _{3} $\end{document} )\begin{document}$ _{2} $\end{document} in the Au\begin{document}$ _{2} $\end{document} @Cu\begin{document}$ _{6} $\end{document} nanocluster can be viewed as a d\begin{document}$ ^{10} $\end{document} -\begin{document}$ \sigma $\end{document} closed-shell interaction. However, chemical bonding analysis shows that there is a ten center-two electron (10c-2e) multicenter bonding between two moieties. Further comparative studies on other bimetallic nanocluster M\begin{document}$ _{2} $\end{document} @Cu\begin{document}$ _{6} $\end{document} (M = Ag, Cu, Zn, Cd, Hg) also revealed that multicenter bonding is the origin of electronic stability of the complexes besides the d\begin{document}$ ^{10} $\end{document} -\begin{document}$ \sigma $\end{document} closed-shell interaction. This will provide valuable insights into the understanding of closed-shell interactions. 相似文献
46.
Yao Chengli Zhu Jinmiao Li Hongying Zheng Bin Wei Yanxin 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2017,91(13):2680-2685
Russian Journal of Physical Chemistry A - Zinc oxide (ZnO) nanostructured materials have received significant attention because of their unique physicochemical and electronic properties. In... 相似文献
47.
Fei Fan Sheng-Jiang Chang Chao Niu Yu Hou Xiang-Hui Wang 《Optics Communications》2012,285(18):3763-3769
The gyromagnetic properties of ferrite materials and the nonreciprocal property of a silicon-ferrite photonic crystal cavity are investigated in the terahertz region. Through the structure optimization and analysis of defect mode coupling, we design a magnetically tunable circulator, of which central operating frequency can be tuned from 180 to 205 GHz and the maximum isolation is 65.2 dB. Moreover, the further study shows that the gyrotropy, dispersion, and ferromagnetic loss of ferrite materials under the different external magnetic fields greatly affect the transmission and isolation property of this device. This circulator is flexible to realize functions of controllable splitting, routing, filtering and isolation by changing the external magnetic field for the THz applications. 相似文献
48.
Measurement-based quantum computation in an optical setup shows great promise towards the implementation oflarge-scale quantum computation. The difficulty of measurement-based quantum computation lies in the preparation ofcluster state. In this paper, we propose the method of generating the large-scale cluster state, which is a platform formeasurement-based quantum computation. In order to achieve more complex quantum circuits, the preparation protocolof N-photon cluster state will be proposed as a generalization of the preparation of four- and five-photon cluster states.Furthermore, our proposal is experimentally feasible. 相似文献
49.
Bing-Sheng Lin 《中国物理 B》2021,30(11):110203-110203
We study the Connes distance of quantum states of two-dimensional (2D) harmonic oscillators in phase space. Using the Hilbert-Schmidt operatorial formulation, we construct a boson Fock space and a quantum Hilbert space, and obtain the Dirac operator and a spectral triple corresponding to a four-dimensional (4D) quantum phase space. Based on the ball condition, we obtain some constraint relations about the optimal elements. We construct the corresponding optimal elements and then derive the Connes distance between two arbitrary Fock states of 2D quantum harmonic oscillators. We prove that these two-dimensional distances satisfy the Pythagoras theorem. These results are significant for the study of geometric structures of noncommutative spaces, and it can also help us to study the physical properties of quantum systems in some kinds of noncommutative spaces. 相似文献
50.
Tunable optomechanically induced transparency and fast–slow light in a loop-coupled optomechanical system 下载免费PDF全文
《中国物理 B》2021,30(9):94205-094205
We theoretically explore the tunability of optomechanically induced transparency(OMIT) phenomenon and fast–slow light effect in a loop-coupled hybrid optomechanical system in which two optical modes are coupled to a common mechanical mode. In the probe output spectrum, we find that the interference phenomena OMIT caused by the optomechanical interactions and the normal mode splitting(NMS) induced by the strong tunnel coupling between the cavities can be observed. We further observe that the tunnel interaction will affect the distance and the heights of the sideband absorption peaks. The results also show that the switch from absorption to amplification can be realized by tuning the driving strength because of the existence of stability condition. Except from modulating the tunnel interaction, the conversion between slow light and fast light also can be achieved by adjusting the optomechanical interaction in the output field. This study may provide a potential application in the fields of high precision measurement and quantum information processing. 相似文献